NULL is supposed to indicate the absence of a value, rather than being thought of as a value itself. It's the empty slot, it's the missing information, it's the unanswered question. It's not a jumped-up zero or empty set.
This is why a variable containing a NULL is considered to be unset: it doesn't have a value. Setting a variable to NULL is telling it to forget its value without providing a replacement value to remember instead. The variable remains so that you can give it a proper value to remember later; this is especially important when the variable is an array element or object property.
It's a bit of semantic awkwardness to speak of a "null value", but if a variable can exist without having a value, the language and implementation have to have something to represent that situation. Because someone will ask. If only to see if the slot has been filled.